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Authors
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Hayar S. Munierlamy C. Chone T. Schiavon M .
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Title
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PHYSICO-CHEMICAL VERSUS MICROBIAL RELEASE OF C-14-ATRAZINE BOUND RESIDUES
FROM A LOAMY CLAY SOIL INCUBATED IN LABORATORY MICROCOSMS
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Source
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Chemosphere. 34(12):2683-2697, 1997 Jun.
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ISSN
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0045-6535
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Author Keywords
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Atrazine. Microcosm. Mineralization. C-14-bound residues.
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KeyWords Plus
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Western tennessee soil. Pesticide-residues. Outdoor conditions. Fulvic-acid.
Atrazine. Degradation. Metabolites. Hydroxyatrazine. Adsorption. Adaptation.
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Abstract
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A loamy clay soil containing unextractable C-14-ring labeled atrazine residues
was incubated in microcosms under abiotic and biotic conditions. The mineralization
activity of the soil microflora was evaluated by the release of total CO2
and (CO2)-C-14. After 63 days of sample incubation the total organic carbon
mineralization was of 1.71%, that of C-14-residues was of 0.72% of the
initial radioactivity. No direct relationship was established between the
mineralization of atrazine residues and the global mineralization. The
contribution of soil microorganisms in the release of C-14-residues was
weak. The availability of non-extractable residues was mainly controlled
by physico-chemical factors. The low value of the reextractability rate
and the distribution of bound residues during the soil sample incubation
shown the active role of organic matter in detoxification procedure. Ninety
percent of the residues remained bound after 63 days of incubation and
were thus, potentially available without biocide activity. The fractionation
of soil organic matter allowed to specify the distribution of bound residues
within the organic compartments. After a long-stay of pesticides in soils,
approximately 65% of bound residues were associated with humin. (C) 1997
Elsevier Science Ltd. [References: 54]
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Language
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English
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Publication Type
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Article
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CC Categories
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Environment/ecology.
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Subset
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Current Contents/Agriculture, Biology & Environmental Sciences
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Institution
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Reprint available from:
Hayar S
CNRS
CTR PEDOL BIOL
17 RUE NOTRE DAME PAUVRES
BP 5
F-54501 VANDOEUVRE LES NANCY
FRANCE
ECOLE NATL SUPER AGRON & IND AGROALIMENTAIRES
F-54501 VANDOEUVRE LES NANCY
FRANCE
UNIV ST ESPRIT KASLIK
FAC SCI AGRON
JOUNIEH
LEBANON